Reseacher

Name SHIOTSUKI Masashi
Official Title Associate Professor
Affiliation Department of Applied Chemistry, Faculty of Science and Technology, Tokyo City University
E-mail mshiotsu@tcu.ac.jp
Web
  1. http://www.ese.tcu.ac.jp/labs/nano2/
  2. https://www.risys.gl.tcu.ac.jp/Main.php?action=profile&type=detail&tchCd=5001946
Profile He received his D. Eng. Degree in 2003 from the Graduate School of Engineering at Kyoto University under the supervision of Professor Take-aki Mitsudo. His research interests include Organic and Polymeric Functional Materials based on Organic Synthesis and the related chemistry such as Membrane Chemistry. Conjugated Polymers, and Transition-metal Catalysis.
Research Field(Keyword & Summary)
  1. Functional Organic/Polymeric Materials

    Research target is to create novel functional organic/polymeric materials by designing molecules with the viewpoints of molecular dynamics. Application of the developed materials can be gas separation membranes, aggregation induced emission materials, and living polymerization initiator/system.

Representative Papers
  1. "A new class of polychlorinated compounds derived from o-chloranil" Tetrahedron Letters, 2020, 61(35), 152268.
  2. "Synthesis of block copolymers using end-functionalized polyacetylenes as macroinitiators", Polymer Chemistry, 2018, 9(28), 3855.
  3. "Transformer of Achiral Amounts to Chirality: Double Reversal of Enantioselectivity Using a Single Cocatalyst in Asymmetric Polymerization", Macromolecules, 2017, 50(19), 7468
  4. "Organocatalytic intermolecular [2+2] cycloaddition of norbornadienes by a stable organic radical compound", 2017, 58(51), 4755
  5. "Synthesis of poly(1-chloro-2-arylacetylene)s with high cis-content and examination of their absorption/emission properties", Polymer Chemistry, 2017, 55(3), 382.
  6. "Chirality amplification in helical block copolymers. Synthesis and chiroptical properties of block copolymers of chiral/achiral acetylene monomers", Polymer Chemistry, 2015, 32(6), 5931.
  7. "Photoinduced Formation of an Azobenzene-Based CD-Active Supramolecular Cyclic Dimer", Chemistry - A European Journal, 2015, 21(18), 6747.
  8. "Synthesis and helical structures of poly(ω-alkynamide)s having chiral side chains: Effect of solvent on their screw-sense inversion", Chemistry - A European Journal, 2014, 24(46), 6633.
  9. "Synthesis of hydrocarbon polymers containing bulky dibenzobicyclic moiety by ROMP and their characteristic optical properties", Journal of Polymer Science, Part A: Polymer Chemistry, 2014, 52(10), 1392.
  10. "New approach to the polymerization of disubstituted acetylenes by bulky monophosphine-ligated palladium catalysts", ACS Macro Letters, 2013, 3(1), 51
Patent
  1. Organic Radical Initiator for Living Polymerization JP2021-1134 2019, June
  2. and the other related patents including JP2012-72124 (2011-August)
  3. JP2013-047198 (2011-August)
  4. JP2012-46706 (2010-August)
  5. WO2006-004161 2004-July
Award EFR Award (TCU)
Grant-in-Aid for Scientific Research Support: Japan Society for Promotion of Science (JSPS) https://nrid.nii.ac.jp/ja/nrid/1000030362453/
Research Grants/Projects including subsidies, donations, grants, etc. Grants-in-Aid for Scientific Research (KAKENHI), Joint Research with a Certain Company.
Recruitment of research assistant(s) N/A
Affiliated academic society (Membership type) Japan Chemical Society, American Chemical Society,
Education Field (Undergraduate level) Organic Chemistry, Polymer Chemistry, Physical Chemistry
Education Field (Graduate level) Functional Molecular Materials

Affiliation